CCQM-K10.2018

MEASURAND   Amount fraction of benzene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

Degrees of equivalence represented by Di = (xi - xR,i ) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in nmol mol-1.

Benzene at 5 nmol mol-1
Di / nmol mol-1
Participating institutes

CCQM-K10.2018

MEASURAND   Amount fraction of toulene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

Degrees of equivalence represented by Di = (xi - xR,i ) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in nmol mol-1.

Toluene at 5 nmol mol-1
Di / nmol mol-1
Participating institutes

CCQM-K10.2018

MEASURAND   Amount fraction of ethylbenzene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

Degrees of equivalence represented by Di = (xi - xR,i ) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in nmol mol-1.

Ethylbenzene at 5 nmol mol-1
Di / nmol mol-1
Participating institutes

CCQM-K10.2018

MEASURAND   Amount fraction of p-Xylene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

Degrees of equivalence represented by Di = (xi - xR,i ) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in nmol mol-1.

p-Xylene at 5 nmol mol-1
Di / nmol mol-1
Participating institutes

**Reported as a combined value for p-xylene and m-xylene as explained in Section 4.3 of the CCQM-K10.2018 Final report

CCQM-K10.2018

MEASURAND   Amount fraction of m-Xylene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

Degrees of equivalence represented by Di = (xi - xR,i ) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in nmol mol-1.

m-Xylene at 5 nmol mol-1
Di / nmol mol-1
Participating institutes

**Reported as a combined value for p-xylene and m-xylene as explained in Section 4.3 of the CCQM-K10.2018 Final report.

CCQM-K10.2018

MEASURAND   Amount fraction of o-Xylene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

Degrees of equivalence represented by Di = (xi - xR,i ) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in nmol mol-1.

o-Xylene at 5 nmol mol-1
Di / nmol mol-1
Participating institutes

CCQM-K10.2018

MEASURAND   Amount fraction of benzene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

Degrees of equivalence represented by Di = (xi - xR,i ) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in nmol mol-1.

LABi Di Uneg,i Upos,i
nmol mol-1
nmol mol-1
nmol mol-1
KRISS 0.005 0.280
LNE 0.500 0.295
NIST 0.135 0.217
NMISA -0.297 0.233
NPL 0.020 0.226
VNIIM 0.530 0.258
VSL 0.041 0.225
METAS 1.119 0.710
UBA -0.001 0.095
CHMI 0.059 0.276
Participating institutes
CCQM-K10.2018

CCQM-K10.2018

MEASURAND   Amount fraction of toulene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

Degrees of equivalence represented by Di = (xi - xR,i ) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in nmol mol-1.

LABi Di Uneg,i Upos,i
nmol mol-1
nmol mol-1
nmol mol-1
KRISS -0.043 0.268
LNE 0.508 0.281
NIST 0.124 0.207
NMISA 0.302 0.224
NPL 0.042 0.218
VNIIM 0.498 0.247
VSL 0.050 0.217
METAS 0.539 0.240
UBA -0.031 0.141
CHMI 0.189 0.254
Participating institutes
CCQM-K10.2018

CCQM-K10.2018

MEASURAND   Amount fraction of ethylbenzene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

Degrees of equivalence represented by Di = (xi - xR,i ) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in nmol mol-1.

LABi Di Uneg,i Upos,i
nmol mol-1
nmol mol-1
nmol mol-1
KRISS -0.133 0.243
LNE 0.515 0.277
NIST 0.108 0.214
NMISA 0.362 0.206
NPL 0.001 0.205
VNIIM 0.555 0.284
VSL 0.096 0.231
METAS 0.522 0.418
UBA -0.148 0.288
CHMI 0.222 0.380
Participating institutes
CCQM-K10.2018

CCQM-K10.2018

MEASURAND   Amount fraction of p-Xylene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

Degrees of equivalence represented by Di = (xi - xR,i ) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in nmol mol-1.

LABi Di Uneg,i Upos,i
nmol mol-1
nmol mol-1
nmol mol-1
KRISS -0.105 0.293
LNE 0.560 0.292
NIST 0.106 0.229
NMISA 0.584 0.219
NPL 0.048 0.216
VNIIM 0.641 0.300
VSL 0.167 0.278
METAS** 1.192 0.296
UBA** -0.008 0.218
CHMI** 0.242 0.474
Participating institutes
CCQM-K10.2018

**Reported as a combined value for p-xylene and m-xylene as explained in Section 4.3 of the CCQM-K10.2018 Final report

CCQM-K10.2018

MEASURAND   Amount fraction of m-Xylene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

Degrees of equivalence represented by Di = (xi - xR,i ) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in nmol mol-1.

LABi Di Uneg,i Upos,i
nmol mol-1
nmol mol-1
nmol mol-1
KRISS -0.119 0.290
LNE 0.595 0.302
NIST 0.111 0.248
NMISA 0.952 0.222
NPL 0.056 0.214
VNIIM 0.700 0.299
VSL 0.177 0.276
METAS** 1.192 0.296
UBA** -0.008 0.218
CHMI** 0.242 0.474
Participating institutes
CCQM-K10.2018

**Reported as a combined value for p-xylene and m-xylene as explained in Section 4.3 of the CCQM-K10.2018 Final report.

CCQM-K10.2018

MEASURAND   Amount fraction of o-Xylene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

Degrees of equivalence represented by Di = (xi - xR,i ) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in nmol mol-1.

LABi Di Uneg,i Upos,i
nmol mol-1
nmol mol-1
nmol mol-1
KRISS -0.249 0.282
LNE 0.472 0.251
NIST 0.114 0.245
NMISA 0.690 0.217
NPL -0.056 0.211
VNIIM 0.565 0.294
VSL 0.043 0.272
METAS 0.617 0.457
UBA -0.163 0.306
CHMI 0.187 0.411
Participating institutes
CCQM-K10.2018
Comparison
Comparison close
CC comparison
Linked comparison
CCQM-K10.2018.1
Metrology area, Sub-field Chemistry and Biology, Gases
Description BTEX in Nitrogen
Time of measurements 2023 - 2024
Status Protocol complete
Measurand Amount-of-substance fractions of BTEX (benzene, toluene, ethylbenzene, p-xylene, m-xylene and o-xylene) in matrix of high-purity nitrogen
5 nmol/mol
Transfer device NPL gas mixture
Comparison type Key Comparison
Consultative Committee CCQM (Consultative Committee for Amount of Substance)
Conducted by CCQM (Consultative Committee for Amount of Substance)
Pilot institute LNE
Laboratoire national de métrologie et d'essais
France
Contact person Tatiana Macé

+33140433853
First Name Last Name
wwww@ww.www +356719836 Institute 1 Institute 1 Khmelnitskiy
Pilot laboratory
LNE

Laboratoire national de métrologie et d'essais, France, EURAMET

METAS

Federal Institute of Metrology, Switzerland, EURAMET

UBA

Umweltbundesamt, Federal Environment Agency, Germany, EURAMET

CCQM-K10.2018

MEASURAND   Amount fraction of benzene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

The key comparison reference values xR,i and their associated standard uncertainty uR,i are computed as described in Section 3.5 (gravimetric study) and Section 4.4 (comparative study) of the CCQM-K10.2018 Final report.

  Labi xR,i uR,i
  nmol mol-1 nmol mol-1
  KRISS 5.101 0.102
  LNE 5.101 0.102
  NIST 5.101 0.102
  NMISA 5.101 0.102
  NPL 5.101 0.102
  VNIIM 5.101 0.102
  VSL 5.101 0.102
  METAS 5.091 0.042
  UBA 5.091 0.042
  CHMI 5.091 0.042

 

The degree of equivalence of laboratory i relative to the key comparison reference value xR,i is given by a pair of terms, both expressed in nmol mol-1:

Di = (xi - xR,) and its expanded uncertainty Ui at a 95 % level of confidence computed as described in Section 3.5.3 (gravimetric study) and Section 4.4.2 (comparative study) of the CCQM-K10.2018 Final report.

CCQM-K10.2018

MEASURAND   Amount fraction of toulene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

The key comparison reference values xR,i and their associated standard uncertainty uR,i are computed as described in Section 3.5 (gravimetric study) and Section 4.4 (comparative study) of the CCQM-K10.2018 Final report.

 

  Labi xR,i uR,i
  nmol mol-1 nmol mol-1
  KRISS 4.907 0.098
  LNE 4.907 0.098
  NIST 4.907 0.098
  NMISA 4.907 0.098
  NPL 4.907 0.098
  VNIIM 4.907 0.098
  VSL 4.907 0.098
  METAS 4.951 0.065
  UBA 4.951 0.065
  CHMI 4.951 0.065

       

The degree of equivalence of laboratory i relative to the key comparison reference value xR,i is given by a pair of terms, both expressed in nmol mol-1:

Di = (xi - xR,) and its expanded uncertainty Ui at a 95 % level of confidence computed as described in Section 3.5.3 (gravimetric study) and Section 4.4.2 (comparative study) of the CCQM-K10.2018 Final report.

CCQM-K10.2018

MEASURAND   Amount fraction of ethylbenzene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

The key comparison reference values xR,i and their associated standard uncertainty uR,i are computed as described in Section 3.5 (gravimetric study) and Section 4.4 (comparative study) of the CCQM-K10.2018 Final report.

 

  Labi xR,i uR,i
  nmol mol-1 nmol mol-1
  KRISS 4.656 0.093
  LNE 4.656 0.093
  NIST 4.656 0.093
  NMISA 4.656 0.093
  NPL 4.656 0.093
  VNIIM 4.656 0.093
  VSL 4.656 0.093
  METAS 4.628 0.115
  UBA 4.628 0.115
  CHMI 4.628 0.115

 

The degree of equivalence of laboratory i relative to the key comparison reference value xR,i is given by a pair of terms, both expressed in nmol mol-1:

Di = (xi - xR,) and its expanded uncertainty Ui at a 95 % level of confidence computed as described in Section 3.5.3 (gravimetric study) and Section 4.4.2 (comparative study) of the CCQM-K10.2018 Final report.

CCQM-K10.2018

MEASURAND   Amount fraction of p-Xylene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

The key comparison reference values xR,i and their associated standard uncertainty uR,i are computed as described in Section 3.5 (gravimetric study) and Section 4.4 (comparative study) of the CCQM-K10.2018 Final report.

 

  Labi xR,i uR,i
  nmol mol-1 nmol mol-1
  KRISS 4.892 0.098
  LNE 4.892 0.098
  NIST 4.892 0.098
  NMISA 4.892 0.098
  NPL 4.892 0.098
  VNIIM 4.892 0.098
  VSL 4.892 0.098
  METAS** 9.808 0.103
  UBA** 9.808 0.103
  CHMI** 9.808 0.103

 

**Reported as a combined value for p-xylene and m-xylene as explained in Section 4.3 of the CCQM-K10.2018 Final report

 

The degree of equivalence of laboratory i relative to the key comparison reference value xR,i is given by a pair of terms, both expressed in nmol mol-1:

Di = (xi - xR,) and its expanded uncertainty Ui at a 95 % level of confidence computed as described in Section 3.5.3 (gravimetric study) and Section 4.4.2 (comparative study) of the CCQM-K10.2018 Final report.

CCQM-K10.2018

MEASURAND   Amount fraction of m-Xylene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

The key comparison reference values xR,i and their associated standard uncertainty uR,i are computed as described in Section 3.5 (gravimetric study) and Section 4.4 (comparative study) of the CCQM-K10.2018 Final report.

 

  Labi xR,i uR,i
  nmol mol-1 nmol mol-1
  KRISS 4.840 0.097
  LNE 4.840 0.097
  NIST 4.840 0.097
  NMISA 4.840 0.097
  NPL 4.840 0.097
  VNIIM 4.840 0.097
  VSL 4.840 0.097
  METAS** 9.808 0.103
  UBA** 9.808 0.103
  CHMI** 9.808 0.103

 

**Reported as a combined value for p-xylene and m-xylene as explained in Section 4.3 of the CCQM-K10.2018 Final report.

 

The degree of equivalence of laboratory i relative to the key comparison reference value xR,i is given by a pair of terms, both expressed in nmol mol-1:

Di = (xi - xR,) and its expanded uncertainty Ui at a 95 % level of confidence computed as described in Section 3.5.3 (gravimetric study) and Section 4.4.2 (comparative study) of the CCQM-K10.2018 Final report.

CCQM-K10.2018

MEASURAND   Amount fraction of o-Xylene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

The key comparison reference values xR,i and their associated standard uncertainty uR,i are computed as described in Section 3.5 (gravimetric study) and Section 4.4 (comparative study) of the CCQM-K10.2018 Final report.

 

  Labi xR,i uR,i
  nmol mol-1 nmol mol-1
  KRISS 4.840 0.097
  LNE 4.840 0.097
  NIST 4.840 0.097
  NMISA 4.840 0.097
  NPL 4.840 0.097
  VNIIM 4.840 0.097
  VSL 4.840 0.097
  METAS 4.763 0.121
  UBA 4.763 0.121
  CHMI 4.763 0.121

 

The degree of equivalence of laboratory i relative to the key comparison reference value xR,i is given by a pair of terms, both expressed in nmol mol-1:

Di = (xi - xR,) and its expanded uncertainty Ui at a 95 % level of confidence computed as described in Section 3.5.3 (gravimetric study) and Section 4.4.2 (comparative study) of the CCQM-K10.2018 Final report.

MEASURAND   Amount fraction of benzene in nitrogen

NOMINAL VALUE  5 nmol mol-1

 

xi   measurement value submitted by laboratory iLabi

ui   combined standard uncertainty of xi

  Labi xi ui
  nmol mol-1 nmol mol-1
  KRISS* 5.11 0.10
  LNE* 5.60 0.11
  NIST* 5.24 0.04
  NMISA* 4.80 0.06
  NPL* 5.12 0.05
  VNIIM* 5.63 0.08
  VSL* 5.14 0.05
  METAS 6.21 0.36
  UBA 5.09 0.02
  CHMI 5.15 0.16

 

*Value is calculated as explained in Section 3.5.2 and Appendix A of the CCQM-K10.2018 Final report.

CCQM-K10.2018

MEASURAND   Amount fraction of toulene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

xi   measured mass fraction reported by laboratory iLabi

ui   combined standard uncertainty of xi

 

  Labi xi ui
  nmol mol-1 nmol mol-1
  KRISS* 4.86 0.10
  LNE* 5.42 0.10
  NIST* 5.03 0.04
  NMISA* 5.21 0.06
  NPL* 4.95 0.05
  VNIIM* 5.41 0.08
  VSL* 4.96 0.05
  METAS 5.49 0.08
  UBA 4.92 0.02
  CHMI 5.14 0.12

 

*Value is calculated as explained in Section 3.5.2 and Appendix A of the CCQM-K10.2018 Final report.

CCQM-K10.2018

MEASURAND   Amount fraction of ethylbenzene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

 

xi   measured mass fraction reported by laboratory iLabi

ui   combined standard uncertainty of xi

 

  Labi xi ui
  nmol mol-1 nmol mol-1
  KRISS* 4.52 0.08
  LNE* 5.17 0.11
  NIST* 4.76 0.06
  NMISA* 5.02 0.05
  NPL* 4.66 0.05
  VNIIM* 5.21 0.11
  VSL* 4.75 0.07
  METAS 5.15 0.07
  UBA 4.48 0.02
  CHMI 4.85 0.13

 

*Value is calculated as explained in Section 3.5.2 and Appendix A of the CCQM-K10.2018 Final report.

CCQM-K10.2018

MEASURAND   Amount fraction of p-Xylene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

 

xi   measured mass fraction reported by laboratory iLabi

ui   combined standard uncertainty of xi

  Labi xi ui
  nmol mol-1 nmol mol-1
  KRISS* 4.79 0.11
  LNE* 5.45 0.11
  NIST* 5.00 0.06
  NMISA* 5.48 0.05
  NPL* 4.94 0.05
  VNIIM* 5.53 0.12
  VSL* 5.06 0.10
  METAS** 11.00 0.11
  UBA** 9.80 0.07
  CHMI** 10.05 0.27

 

*Value is calculated as explained in Section 3.5.2 and Appendix A of the Final Report.

**Reported as a combined value for p-xylene and m-xylene as explained in Section 4.3 of the CCQM-K10.2018 Final report

CCQM-K10.2018

MEASURAND   Amount fraction of m-Xylene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

 

xi   measured mass fraction reported by laboratory iLabi

ui   combined standard uncertainty of xi

 

  Labi xi ui
  nmol mol-1 nmol mol-1
  KRISS* 4.72 0.11
  LNE* 5.44 0.12
  NIST* 4.95 0.08
  NMISA* 5.79 0.06
  NPL* 4.90 0.05
  VNIIM* 5.54 0.12
  VSL* 5.02 0.10
  METAS** 11.00 0.11
  UBA** 9.80 0.07
  CHMI** 10.05 0.27

 

*Value is calculated as explained in Section 3.5.2 and Appendix A of the CCQM-K10.2018 Final report.

**Reported as a combined value for p-xylene and m-xylene as explained in Section 4.3 of the CCQM-K10.2018 Final report.

CCQM-K10.2018

MEASURAND   Amount fraction of o-Xylene in nitrogen

NOMINAL VALUE 5 nmol mol-1

 

xi   measured mass fraction reported by laboratory iLabi

ui   combined standard uncertainty of xi

 

  Labi xi ui
  nmol mol-1 nmol mol-1
  KRISS* 4.59 0.11
  LNE* 5.31 0.08
  NIST* 4.95 0.08
  NMISA* 5.53 0.05
  NPL* 4.78 0.05
  VNIIM* 5.41 0.12
  VSL* 4.88 0.10
  METAS 5.38 0.10
  UBA 4.60 0.03
  CHMI 4.95 0.15

 

*Value is calculated as explained in Section 3.5.2 and Appendix A of the CCQM-K10.2018 Final report.