CCQM-K73.2018
MEASURAND Amount content of H+ in hydrochloric acid solutions
NOMINAL VALUE 0.1 mol/kg
Degrees of equivalence represented by Di = (xI - xR) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in mol/kg
CCQM-K73.2018
MEASURAND Amount content of H+ in hydrochloric acid solutions
NOMINAL VALUE 0.1 mol/kg
Degrees of equivalence represented by Di = (xI - xR) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in mol/kg
LABi | Di | Uneg,i | Upos,i | |
---|---|---|---|---|
mol/kg |
mol/kg |
mol/kg |
||
CENAM | 0.0000052 | 0.0000286 | ||
CMI | -0.0000081 | 0.0000279 | ||
DFM | -0.0000002 | 0.0000272 | ||
GUM | 0.0000176 | 0.0000391 | ||
INM | 0.000025 | 0.000176 | ||
INMETRO | 0.0000134 | 0.0000634 | ||
INTI | 0.00020 | 0.00027 | ||
KRISS | 0.0000085 | 0.0000348 | ||
LNE | 0.00017 | 0.00031 | ||
NIM | 0.000007 | 0.000034 | ||
NMIJ | 0.0000155 | 0.0000309 | ||
PTB | -0.0000092 | 0.0000285 | ||
SMU | -0.0000041 | 0.0000297 | ||
UME | -0.000076 | 0.000035 | ||
UNIIM | 0.000071 | 0.000047 | ||
VNIIFTRI | 0.000076 | 0.000216 | ||
CENAM additional | -0.0000037 | 0.0000406 | ||
KRISS additional | 0.0000085 | 0.0000348 | ||
NIM additional | 0.000005 | 0.000104 | ||
PTB additional | 0.0000059 | 0.0000826 | ||
SMU additional | 0.0000187 | 0.0000495 |
Metrology area, Sub-field | Chemistry and Biology, Electrochemistry |
Description | Amount content of H+ in an HCl solution |
Time of measurements | 2022 |
Status | Abandoned |
Measurand | Amount content of strong acid ~ 0.1 mol/kg |
Comparison type | Key Comparison |
Consultative Committee | CCQM (Consultative Committee for Amount of Substance) |
Conducted by | CCQM (Consultative Committee for Amount of Substance) |
Comments | The key comparison CCQM-K73.2018.1 is a subsequent comparison to CCQM K73.2018. It will be performed to demonstrate the capability of the participating institutes to measure the amount content of H+ in a HCl solution with a nominal molality of 0.1 mol/kg. |
Pilot institute |
SMU
Slovensky Metrologicky Ustav Slovakia |
Contact person | Michal Mariassy +421 2 602 94 522 |
Additional |
Pilot laboratory | |
---|---|
SMU |
Slovensky Metrologicky Ustav, Slovakia, EURAMET |
SE "Ukrmetrteststandard" |
State Enterprise "Ukrmetrteststandard", Ukraine, EURAMET |
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CCQM-K73.2018
MEASURAND Amount content of H+ in hydrochloric acid solutions
NOMINAL VALUE 0.1 mol/kg
The key comparison reference value xR and its associated standard uncertainty uR are computed user the DerSimonian Laird estimator of the reported results
xR = 0.1001112 mol/kg uR = 0.0000081 mol/kg
The degree of equivalence of laboratory i relative to the key comparison reference value xR is given by a pair of terms, both expressed in mol/kg:
Di = (xi - xR) and its expanded uncertainty Ui at a 95 % level of confidence where Ui = 2 ui.
CCQM-K73.2018
MEASURAND Amount content of H+ in hydrochloric acid solutions
NOMINAL VALUE 0.1 mol/kg
xi measurement value reported by laboratory i, Labi
ui combined standard uncertainy of xi
kLabi coverage factor reported by laboratory i,
ULabi expanded uncertainty of xi at 95 % level of confidence where Ui = kLabiui
Labi | xi* | ULabi | kLabi |
mol/kg | mol/kg | ||
CENAM | 0.1001164 | 0.0000057 | 2.076 |
CMI | 0.1001031 | 0.0000053 | 2.028 |
DFM | 0.1001110 | 0.0000032 | 2.000 |
GUM | 0.100129 | 0.000028 | 2.000 |
INM | 0.100136 | 0.000173 | 2.366 |
INMETRO | 0.1001245 | 0.0000569 | 2.072 |
INTI | 0.10031 | 0.00026 | 2.429 |
KRISS | 0.1001197 | 0.0000114 | 2.429 |
LNE | 0.10028 | 0.00031 | 2.366 |
NIM | 0.100118 | 0.000015 | 2.212 |
NMIJ | 0.1001267 | 0.0000122 | 2.105 |
PTB | 0.1001020 | 0.0000083 | 2.019 |
SMU | 0.1001071 | 0.0000122 | 2.000 |
UME | 0.100035 | 0.000015 | 2.012 |
UNIIM | 0.100182 | 0.000038 | 2.869 |
VNIIFTRI | 0.100187 | 0.000212 | 2.012 |
* corrected for drift |
Labi | xi** | ULabi | kLabi |
mol/kg | mol/kg | ||
CENAM | 0.1001075 | 0.0000142 | 2.140 |
KRISS | 0.1001197 | 0.0000114 | 2.429 |
NIM | 0.100116 | 0.000093 | 2.649 |
PTB | 0.1001171 | 0.0000743 | 2.025 |
SMU | 0.1001299 | 0.0000345 | 2.000 |
**result of diluted solution, corrected for drift |