CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               15 °C

 

Degrees of equivalence represented by Di = pai0 xR and its expanded uncertainty Ui at a 95 % level of confidence, both in dimensionless units.

pa0 at 15 °C
Di
Participating institutes

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               25 °C

 

Degrees of equivalence represented by Di = pai0 xR and its expanded uncertainty Ui at a 95 % level of confidence, both in dimensionless units.

pa0 at 25 °C
Di
Participating institutes

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               37 °C

 

Degrees of equivalence represented by Di = pai0 xR and its expanded uncertainty Ui at a 95 % level of confidence, both in dimensionless units.

pa0 at 37 °C
Di
Participating institutes

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               5 °C

 

Degrees of equivalence represented by Di = pai0 xR and its expanded uncertainty Ui at a 95 % level of confidence, both in dimensionless units.

pa0 at 5 °C
Di
Participating institutes

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               50 °C

 

Degrees of equivalence represented by Di = pai0 xR and its expanded uncertainty Ui at a 95 % level of confidence, both in dimensionless units.

pa0 at 50 °C
Di
Participating institutes

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               15 °C

 

Degrees of equivalence represented by Di = pai0 xR and its expanded uncertainty Ui at a 95 % level of confidence, both in dimensionless units.

LABi Di Uneg,i Upos,i
(dimensionless)
(dimensionless)
(dimensionless)
BFKH -0.0016 0.0054
BIM 0.0021 0.0036
CMI -0.0114 0.0026
GUM -0.0030 0.0029
INMETRO 0.0023 0.0021
LATU 0.0151 0.0112
NIM 0.0009 0.0034
NIMT 0.0021 0.0106
NMIJ -0.0013 0.0022
PTB -0.0010 0.0015
SMU 0.0024 0.0027
SE"Ukrmetrteststandard" 0.0331 0.0049
VNIIFTRI 0.0008 0.0035
BFKH 0.0037 0.0037
BIM -0.0062 0.0047
CENAM 0.0183 0.0080
GUM 0.0054 0.0034
INACAL 0.0193 0.0075
INM (CO) -0.0335 0.0411
NMI (MD) 0.0155 0.0960
IPQ -0.0022 0.0052
LACOMET 0.0006 0.0042
LNE -0.0023 0.0036
NIMT -0.0127 0.0086
SASO-NMCC -0.0946 0.0059
SNSU-BSN 0.0165 0.0048
SE"Ukrmetrteststandard" 0.0221 0.0043
Participating institutes
CCQM-K19.2018
EURAMET.QM-K19.2018

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               25 °C

 

Degrees of equivalence represented by Di = pai0 xR and its expanded uncertainty Ui at a 95 % level of confidence, both in dimensionless units.

LABi Di Uneg,i Upos,i
(dimensionless)
(dimensionless)
(dimensionless)
BFKH -0.0080 0.0063
BIM 0.0040 0.0039
CMI -0.0173 0.0028
GUM -0.0025 0.0028
IBMETRO 0.0471 0.0104
INMETRO 0.0029 0.0030
INTI 0.0040 0.0798
LATU 0.0146 0.0113
NIM 0.0000 0.0035
NIMT -0.0080 0.0085
NMIJ -0.0010 0.0024
PTB 0.0000 0.0017
SMU 0.0027 0.0033
SE"Ukrmetrteststandard" 0.0279 0.0050
VNIIFTRI -0.0001 0.0036
BFKH 0.0004 0.0037
BIM -0.0068 0.0046
CENAM 0.0230 0.0055
GUM 0.0005 0.0028
IBMETRO -0.0097 0.0301
INACAL 0.0127 0.0065
INM (CO) -0.0327 0.0321
NMI (MD) -0.0007 0.0940
IPQ -0.0077 0.0043
LACOMET -0.0001 0.0040
LATU -0.0047 0.0099
LNE -0.0012 0.0045
NIMT -0.0164 0.0084
SASO-NMCC -0.0017 0.0058
SNSU-BSN 0.0123 0.0047
SE"Ukrmetrteststandard" 0.0172 0.0054
Participating institutes
CCQM-K19.2018
EURAMET.QM-K19.2018

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               37 °C

 

Degrees of equivalence represented by Di = pai0 xR and its expanded uncertainty Ui at a 95 % level of confidence, both in dimensionless units.

LABi Di Uneg,i Upos,i
(dimensionless)
(dimensionless)
(dimensionless)
BFKH -0.0066 0.0039
BIM 0.0035 0.0037
CMI -0.0132 0.0032
GUM -0.0025 0.0028
INMETRO 0.0023 0.0028
LATU 0.0176 0.0106
NIM -0.0029 0.0035
NIMT -0.0054 0.0089
NMIJ -0.0004 0.0024
PTB 0.0006 0.0015
SMU 0.0023 0.0037
SE"Ukrmetrteststandard" 0.0227 0.0058
VNIIFTRI 0.0004 0.0036
BFKH -0.0034 0.0039
BIM -0.006 0.0046
CENAM 0.0210 0.0081
GUM -0.0025 0.0031
INACAL 0.0075 0.0074
INM (CO) -0.0774 0.0391
NMI (MD) 0.0706 0.0980
IPQ -0.0064 0.0045
LACOMET 0.0009 0.0042
LNE -0.0024 0.0051
NIMT -0.0231 0.0078
SASO-NMCC 0.0871 0.0057
SE"Ukrmetrteststandard" 0.0082 0.0059
Participating institutes
CCQM-K19.2018
EURAMET.QM-K19.2018

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               5 °C

 

Degrees of equivalence represented by Di = pai0 xR and its expanded uncertainty Ui at a 95 % level of confidence, both in dimensionless units.

LABi Di Uneg,i Upos,i
(dimensionless)
(dimensionless)
(dimensionless)
GUM -0.0010 0.0030
PTB 0.0001 0.0008
SE"Ukrmetrteststandard" 0.0408 0.0054
VNIIFTRI 0.0007 0.0032
GUM -0.0005 0.0027
NMIJ -0.0072 0.0029
Participating institutes
CCQM-K19.2018
EURAMET.QM-K19.2018

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               50 °C

 

Degrees of equivalence represented by Di = pai0 xR and its expanded uncertainty Ui at a 95 % level of confidence, both in dimensionless units.

LABi Di Uneg,i Upos,i
(dimensionless)
(dimensionless)
(dimensionless)
GUM -0.0043 0.0031
PTB 0.0006 0.0018
SMU 0.0015 0.0037
SE"Ukrmetrteststandard" 0.0242 0.0048
VNIIFTRI 0.0002 0.0039
GUM -0.0005 0.0027
NMIJ -0.0072 0.0029
Participating institutes
CCQM-K19.2018
EURAMET.QM-K19.2018
Comparison
Comparison close
CC comparison
Linked comparison
CCQM-K19.2018.1
Metrology area, Sub-field Chemistry and Biology, Electrochemistry
Description pH measurement of borate buffer solutions
 
Time of measurements 2021 - 2022
Status Abandoned
Measurand pH
~ 9.2
Parameters Temperature : 15 °C, 25 °C, 37 °C and optionally at 5 °C and 50 °C.
Comparison type Key Comparison
Consultative Committee CCQM (Consultative Committee for Amount of Substance)
Conducted by CCQM (Consultative Committee for Amount of Substance)
Comments This comparison was declared as Abandoned and was archived on 03 September 2025.
Pilot institute VNIIFTRI
Institute of Physical Technical and Radiotechnical Measurements, Rosstandart
Russian Federation
Contact person Narine Oganyan

+79017227886
Additional
First Name Last Name
wwww@ww.www +356719836 Institute 1 Institute 1 Khmelnitskiy
Pilot laboratory
VNIIFTRI

Institute of Physical Technical and Radiotechnical Measurements, Rosstandart, Russian Federation, COOMET

CENAM

Centro Nacional de Metrologia, Mexico, SIM

CMI

Czech Metrology Institute, Czechia, EURAMET

DFM

Danish Fundamental Metrology A/S, Denmark, EURAMET

IBMETRO

Instituto Boliviano de Metrología, Bolivia, SIM

INACAL

National Institute for Quality, Peru, SIM

INM (CO)

Instituto Nacional de Metrología de Colombia, Colombia, SIM

IPQ

Instituto Portugues da Qualidade, Portugal, EURAMET

LATU

Laboratorio Tecnologico del Uruguay, Uruguay, SIM

NIMT

National Institute of Metrology (Thailand), Thailand, APMP

NIST

National Institute of Standards and Technology, United States, SIM

NMIJ AIST

National Metrology Institute of Japan, Japan, APMP

PTB

Physikalisch-Technische Bundesanstalt, Germany, EURAMET

SE "Ukrmetrteststandard"

State Enterprise "Ukrmetrteststandard", Ukraine, EURAMET

SNSU-BSN

National Measurement Standard - National Standardization Agency of Indonesia, Indonesia, APMP

UME

TÜBITAK Ulusal Metroloji Enstitüsü, Türkiye, EURAMET

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               15 °C

 

The key comparison reference value xR and its associated standard uncertainty uR are computed from a weighted mean with dispersion of results obtained using primary method, excluding results of CMI and UkrCSM.

        xR = 9.31263     uR = 0.00059

 

The degree of equivalence of laboratory i relative to the key comparison reference value xR is given by a pair of terms, both expressed in dimensionless units:

Di = pai0 xR  and its expanded uncertainty Ui  at a 95 % level of confidence (k = 2) (see page 30 of the CCQM-K19.2018 Final report), where pai0 represents the acidity function at zero chloride molality at 15 °C

 

Linking EURAMET.QM-K19.2018 to CCQM-K19.2018

NMIJ and PTB provide the link between the key comparison CCQM-K19.2018 and EURAMET.QM-K19.2018, having participated in both comparisons. The linking process is described in Section 9 of the EURAMET.QM-K19.2018 Final report.

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               25 °C

 

The key comparison reference value xR and its associated standard uncertainty uR are computed from a weighted mean with dispersion of results obtained using primary method, excluding results of CMI and UkrCSM.

        xR = 9.22050     uR = 0.00073

 

The degree of equivalence of laboratory i relative to the key comparison reference value xR is given by a pair of terms, both expressed in dimensionless units:

Di = pai0 xR  and its expanded uncertainty Ui  at a 95 % level of confidence (k = 2) (see page 30 of the CCQM-K19.2018 Final report), where pai0 represents the acidity function at zero chloride molality at 25 °C

 

Linking EURAMET.QM-K19.2018 to CCQM-K19.2018

NMIJ and PTB provide the link between the key comparison CCQM-K19.2018 and EURAMET.QM-K19.2018, having participated in both comparisons. The linking process is described in Section 9 of the EURAMET.QM-K19.2018 Final report.

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               37 °C

 

The key comparison reference value xR and its associated standard uncertainty uR are computed from a weighted mean with dispersion of results obtained using primary method, excluding results of CMI and UkrCSM.

        xR = 9.13210     uR = 0.00072

 

The degree of equivalence of laboratory i relative to the key comparison reference value xR is given by a pair of terms, both expressed in dimensionless units:

Di = pai0 xR  and its expanded uncertainty Ui  at a 95 % level of confidence (k = 2) (see page 30 of the CCQM-K19.2018 Final report), where pai0 represents the acidity function at zero chloride molality at 37 °C

 

Linking EURAMET.QM-K19.2018 to CCQM-K19.2018

NMIJ and PTB provide the link between the key comparison CCQM-K19.2018 and EURAMET.QM-K19.2018, having participated in both comparisons. The linking process is described in Section 9 of the EURAMET.QM-K19.2018 Final report.

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               5 °C

 

The key comparison reference value xR and its associated standard uncertainty uR are computed from a weighted mean without dispersion of results obtained using primary method, excluding results of CMI and UkrCSM.

        xR = 9.42462     uR = 0.00060

 

The degree of equivalence of laboratory i relative to the key comparison reference value xR is given by a pair of terms, both expressed in dimensionless units:

Di = pai0 xR  and its expanded uncertainty Ui  at a 95 % level of confidence (k = 2) (see page 30 of the CCQM-K19.2018 Final report), where pai0 represents the acidity function at zero chloride molality at 5 °C

 

Linking EURAMET.QM-K19.2018 to CCQM-K19.2018

PTB provides the link between the key comparison CCQM-K19.2018 and EURAMET.QM-K19.2018, having participated in both comparisons. The linking process is described in Section 9 of the EURAMET.QM-K19.2018 Final report.

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               50 °C

 

The key comparison reference value xR and its associated standard uncertainty uR are computed from a weighted mean with dispersion of results obtained using primary method, excluding results of CMI and UkrCSM.

        xR = 9.05801     uR = 0.00097

 

The degree of equivalence of laboratory i relative to the key comparison reference value xR is given by a pair of terms, both expressed in dimensionless units:

Di = pai0 xR  and its expanded uncertainty Ui  at a 95 % level of confidence (k = 2) (see page 30 of the CCQM-K19.2018 Final report), where pai0 represents the acidity function at zero chloride molality at 50 °C

 

Linking EURAMET.QM-K19.2018 to CCQM-K19.2018

PTB provides the link between the key comparison CCQM-K19.2018 and EURAMET.QM-K19.2018, having participated in both comparisons. The linking process is described in Section 9 of the EURAMET.QM-K19.2018 Final report.

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               15 °C

 

CCQM-K19.2018

xi   measurement result reported by laboratory iLabi

ui   combined standard uncertainty of xi

  Labi xi ui
  (dimensionless) (dimensionless)
  BFKH 9.3110 0.0027
  BIM 9.3147 0.0018
  CMI 9.3012 0.0012
  GUM 9.3096 0.0014
  INMETRO 9.3149 0.0010
  LATU 9.3277 0.0056
  NIM 9.3135 0.0017
  NIMT 9.3147 0.0053
  NMIJ 9.3113 0.0011
  PTB 9.3116 0.0007
  SMU 9.3150 0.0013
  SE"Ukrmetrteststandard" 9.3457 0.0024
  VNIIFTRI 9.3134 0.0017

 

 

EURAMET.QM-K19.2018

The measurement results are listed in in Section 7 of the EURAMET.QM-K19.2018 Final report.

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               25 °C

 

CCQM-K19.2018

xi   measurement result reported by laboratory iLabi

ui   combined standard uncertainty of xi

  Labi xi ui
  (dimensionless) (dimensionless)
  BFKH 9.2125 0.0031
  BIM 9.2245 0.0019
  CMI 9.2032 0.0012
  GUM 9.2177 0.0013
  IBMETRO 9.2680 0.0050
  INMETRO 9.2234 0.0014
  INTI 9.2244 0.0400
  LATU 9.2351 0.0056
  NIM 9.2205 0.0017
  NIMT 9.2125 0.0042
  NMIJ 9.2195 0.0011
  PTB 9.2205 0.0007
  SMU 9.2232 0.0016
  SE"Ukrmetrteststandard" 9.2484 0.0024
  VNIIFTRI 9.2204 0.0017

 

 

EURAMET.QM-K19.2018

The measurement results are listed in in Section 7 of the EURAMET.QM-K19.2018 Final report.

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               37 °C

 

CCQM-K19.2018

xi   measurement result reported by laboratory iLabi

ui   combined standard uncertainty of xi

  Labi xi ui
  (dimensionless) (dimensionless)
  BFKH 9.1255 0.0019
  BIM 9.1356 0.0018
  CMI 9.1189 0.0014
  GUM 9.1296 0.0013
  INMETRO 9.1344 0.0013
  LATU 9.1497 0.0053
  NIM 9.1292 0.0017
  NIMT 9.1267 0.0044
  NMIJ 9.1317 0.0011
  PTB 9.1327 0.0006
  SMU 9.1344 0.0018
  SE"Ukrmetrteststandard" 9.1548 0.0028
  VNIIFTRI 9.1325 0.0017

 

 

EURAMET.QM-K19.2018

The measurement results are listed in in Section 7 of the EURAMET.QM-K19.2018 Final report.

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               5 °C

 

CCQM-K19.2018

xi   measurement result reported by laboratory iLabi

ui   combined standard uncertainty of xi

  Labi xi ui
  (dimensionless) (dimensionless)
  GUM 9.4236 0.0016
  PTB 9.4247 0.0007
  SE"Ukrmetrteststandard" 9.4654 0.0026
  VNIIFTRI 9.4253 0.0017

 

 

EURAMET.QM-K19.2018

The measurement results are listed in in Section 7 of the EURAMET.QM-K19.2018 Final report.

CCQM-K19.2018 and EURAMET.QM-K19.2018

MEASURAND           pH of borate buffer solutions

NOMINAL VALUE         9.2

TEMPERATURE               5 °C

 

CCQM-K19.2018

xi   measurement result reported by laboratory iLabi

ui   combined standard uncertainty of xi

  Labi xi ui
  (dimensionless) (dimensionless)
  GUM 9.0537 0.0014
  PTB 9.0586 0.0006
  SMU 9.0595 0.0017
  SE"Ukrmetrteststandard" 9.0822 0.0022
  VNIIFTRI 9.0582 0.0018

 

 

EURAMET.QM-K19.2018

The measurement results are listed in in Section 7 of the EURAMET.QM-K19.2018 Final report.