MEASURAND     Mass fraction of Deoxynivalenol (DON) in acetonitrile (ACN)

NOMINAL RANGE   9 mg/kg to 125 mg/kg

 

Degrees of equivalence represented by Di = (xI - xRi) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in mg/kg.

Mass fraction of Deoxynivalenol (DON) in acetonitrile (ACN)
Di / (mg/kg)
Participating institutes

The samples are indicated by A and B.

(CBKT) – sample provided by the laboratory is prepared using a value assigned stock solution of DON in ACN supplied within the "Metrology for Safe Food and Feed in Developing Economies" Capacity Building Programme;
(own) – sample provided by the laboratory is prepared based on the laboratory’s own characterized source material.

MEASURAND     Mass fraction of Deoxynivalenol (DON) in acetonitrile (ACN)

NOMINAL RANGE   9 mg/kg to 125 mg/kg

 

Degrees of equivalence represented by Di = (xI - xRi) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in mg/kg.

LABi Di Uneg,i Upos,i
mg/kg
mg/kg
mg/kg
INM (CBKT) A -0.06 0.75
INM (CBKT) B -0.14 0.63
NIMT (CBKT) A 0.12 0.67
NIMT (CBKT) B 0.16 0.68
UME (CBKT) A 0.12 0.98
UME (CBKT) B 0.04 1.09
NIM (own) A 0.41 1.55
NIM (own) B 1.36 1.60
NIM (CBKT) A 0.33 1.49
NIM (CBKT) B 0.17 1.69
INMETRO (CBKT) A 0.11 1.81
INMETRO (CBKT) B 0.42 2.04
LATU (CBKT) A -0.95 2.43
LATU (CBKT) B 0.64 2.40
INTI (CBKT) A 1.26 2.66
INTI (CBKT) B 1.26 2.41
NRC (own) A 1.66 2.50
NRC (own) B 1.90 2.23
NMISA (own) A -4.25 5.64
NMISA (own) B -2.01 5.49
Participating institutes
CCQM-K154.c

The samples are indicated by A and B.

(CBKT) – sample provided by the laboratory is prepared using a value assigned stock solution of DON in ACN supplied within the "Metrology for Safe Food and Feed in Developing Economies" Capacity Building Programme;
(own) – sample provided by the laboratory is prepared based on the laboratory’s own characterized source material.

Comparison
Comparison close
CC comparison
Linked comparison
CCQM-K154.c
Metrology area, Sub-field Chemistry and Biology, Organics
Description Deoxynivalenol (DON) in acetonitrile (ACN)
Time of measurements 2021 - 2022
Status Approved for equivalence
Final Reports of the comparisons
Measurand Mass fraction
mg/kg
Comparison type Key Comparison
Consultative Committee CCQM (Consultative Committee for Amount of Substance)
Conducted by CCQM (Consultative Committee for Amount of Substance)
Comments Gravimetric preparation and value assignment of deoxynivalenol (DON) in acetonitrile (ACN).
 
Pilot institute BIPM
Bureau International des Poids et Mesures
BIPM - International Organization
Contact person R. Josephs

+33 (0) 1 45 07 70 55
First Name Last Name
wwww@ww.www +356719836 Institute 1 Institute 1 Khmelnitskiy
Pilot laboratory
BIPM

Bureau International des Poids et Mesures, BIPM - International Organization, N/A

INM (CO)

Instituto Nacional de Metrología de Colombia, Colombia, SIM

INMETRO

Instituto Nacional de Metrologia, Qualidade e Tecnologia, Brazil, SIM

INTI

Instituto Nacional de Tecnologia Industrial, Argentina, SIM

LATU

Laboratorio Tecnologico del Uruguay, Uruguay, SIM

NIM

National Institute of Metrology, China, APMP

NIMT

National Institute of Metrology (Thailand), Thailand, APMP

NMISA

National Metrology Institute of South Africa, South Africa, AFRIMETS

NRC

National Research Council, Canada, SIM

UME

TÜBITAK Ulusal Metroloji Enstitüsü, Türkiye, EURAMET

MEASURAND     Mass fraction of Deoxynivalenol (DON) in acetonitrile (ACN)

NOMINAL RANGE   9 mg/kg to 125 mg/kg

 

For each sample preparation, the value of the DON mass fraction, xRi,  assigned by the BIPM according to the calibration procedure described in the Final report, and its associated combined uncertainty, uRi,  is taken as the key comparison reference value for laboratory i.

Labi xR,i uR,i
  mg/kg mg/kg
INM (CBKT) A 10.06 0.34
INM (CBKT) B 10.14 0.27
NIMT (CBKT) A 9.92 0.27
NIMT (CBKT) B 9.88 0.28
UME (CBKT) A 20.44 0.37
UME (CBKT) B 20.52 0.44
NIM (own) A 31.83 0.60
NIM (own) B 30.88 0.63
NIM (CBKT) A 31.02 0.49
NIM (CBKT) B 31.18 0.63
INMETRO (CBKT) A 30.09 0.61
INMETRO (CBKT) B 29.78 0.77
LATU (CBKT) A 40.83 0.75
LATU (CBKT) B 39.24 0.72
INTI (CBKT) A 53.55 0.98
INTI (CBKT) B 53.55 0.80
NRC (own) A 54.94 0.96
NRC (own) B 54.70 0.78
NMISA (own) A 123.45 2.03
NMISA (own) B 121.21 1.92

       

For each sample, the degree of equivalence of each laboratory i with respect to the reference value is given by a pair of terms both expressed in mg/kg:

Di = (xi - xRi ) and Ui, its expanded uncertainty at a 95% level of confidence, Ui = 2(ui 2 + uRi 2)1/2   

 

MEASURAND     Mass fraction of Deoxynivalenol (DON) in acetonitrile (ACN)

NOMINAL RANGE   9 mg/kg to 125 mg/kg

xi   measurement value submitted by laboratory iLabi

ui   combined standard uncertainty of xi

  Labi xi ui
    mg/kg mg/kg
  INM (CBKT) A 10.00 0.16
  INM (CBKT) B 10.00 0.16
  NIMT (CBKT) A 10.04 0.195
  NIMT (CBKT) B 10.04 0.195
  UME (CBKT) A 20.56 0.32
  UME (CBKT) B 20.56 0.32
  NIM (own) A 32.24 0.49
  NIM (own) B 32.24 0.49
  NIM (CBKT) A 31.35 0.56
  NIM (CBKT) B 31.35 0.56
  INMETRO (CBKT) A 30.2 0.669
  INMETRO (CBKT) B 30.2 0.669
  LATU (CBKT) A 39.876 0.958
  LATU (CBKT) B 39.876 0.958
  INTI (CBKT) A 54.81 0.90
  INTI (CBKT) B 54.81 0.90
  NRC (own) A 56.6 0.8
  NRC (own) B 56.6 0.8
  NMISA (own) A 119.2 1.96
  NMISA (own) B 119.2 1.96

 

The samples are indicated by A and B.

(CBKT) – sample provided by the laboratory is prepared using a value assigned stock solution of DON in ACN supplied within the "Metrology for Safe Food and Feed in Developing Economies" Capacity Building Programme;
(own) – sample provided by the laboratory is prepared based on the laboratory’s own characterized source material.